I took some time to do a simple test of the focusing accuracy of my Canon 5D Mark III as follows:
i) I took a regular shot using phase detection focusing (non-liveview).
ii) I then immediately switched to contrast detection (liveview) and bumped up magnification 10x.
iii) I depressed the shutter button half way. The focus did not change at all.
I was very happy with the results of the test. Focus was bang on and the photo looked sharp.
I then used DPP to boost sharpness from an in-camera default of "3" to the maximum "10". The following photos show results of the post processing. EXIF Data can be found following the photos.
FULL PHOTO - SHARPENED IN DPP TO "10":
100% CROP:
BEFORE POST PROCESSING AND AFTER PROCESSING:
EXIF Data:
Camera Model:    Canon EOS 5D Mark III
Shooting Mode:    Aperture-Priority AE
Tv( Shutter Speed ):    1/100
Av( Aperture Value ):    3.2
Metering Mode:    Evaluative Metering
Exposure Compensation:    0
ISO Speed:    125
Auto ISO Speed:    ON
Lens:    EF100mm f/2.8 Macro USM
Focal Length:    100.0mm
Image Size:    5760x3840
Image Quality:    RAW
White Balance Mode:    Auto
AF Mode:    One-Shot AF
AF area select mode:    Spot AF
Picture Style:    Standard
Sharpness:    3
Contrast:    0
Saturation:    0
Color tone:    0
Color Space:    sRGB
Live View Shooting:    OFF