Sorry, accidentally pressed send (on Iphone app)
I am not sure how this photo is taken, I will tell you how I would do it that may explain the 2 flashes. It took me a while to figure this out some years ago and now this is what I do whenever I need to shoot a night scene portrait. BTW, P&S has this mode.
I am a Canon user, so some of my terms used are specific to Canon.
1. Get the background exposure, either shutter or aperture priority.
2. Switch to manual mode, duplicate the settings and take a few with tweaks, adjusting to what you really like
3. Set up the flash. Depending situation and what you have. Remote triggers and / or diffuses.
4. Get you subject in front.
5. Still on the manual setting aim at subject wand press the * or exposure lock button. This will trigger the flash.
6. Recompose and shoot. The flash triggers the second time
7. I have to assumed that the flash is still aiming at the subject at the same angle, camera is on a tripod and flash is on ETTL mode.
I hope his helps.