In photoshop,
1. View --> Proof Setup --> Monitor RGB
2. CTRY-Y (or View --> Proof Colors)
Each time you hit CTRL-Y you are turing the image soft proof 'on' and 'off'. Pay attention to the area where the white stripes are and you should see a slight shift from pale purple to deep blue. Certainly its not the bright purple as above which is from an edited image where I believe during the editing workflow, the Green and Blue channel were clipped and not the Red channel. The histogram shows that the Green and Red channels were much closer to the right hand side than the Red channel.
If you use Image -- > Adjustment --> Color Balance in photoshop and move the Red slider to say -30, the 'pruple' will turn 'blue' as shown in the original post (right hand image).
It is quite interesting that the original poster raised this discussion because unless you get hit onto it, it is easily missed. My opinion are that even if you shoot in sRGB, its always best to convert to Adobe RGB and 16 bits when you do color editing work where good color reproduction is important. Once editing is done, its alright to convert back to sRGB and 8 bits to save. Nothing to loose but avoids potential issues like this one.
I actually found out about this Adobe RGB/16 bits the long way. Did a lot of prints with various combinations and color patches and its quite evident that converting to sRGB will shift colors particularly reds. Nowadays even when I send my images for outside printing its always on Adobe RGB color space. Most digital printers (Kodak Noritsu, Fuji Frontier) can print much bigger than the sRGB color space.